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1 article(s) from Lu, Song-Bo

A conformationally adaptive macrocycle: conformational complexity and host–guest chemistry of zorb[4]arene

Liu-Pan Yang,
Song-Bo Lu,
Arto Valkonen,
Fangfang Pan,
Kari Rissanen and
Wei Jiang

Beilstein J. Org. Chem. 2018, 14, 1570–1577, doi:10.3762/bjoc.14.134

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Graphical Abstract

Scheme 1: (a) Chemical structures of ZB4 and the guests involved in this research. The counterions are PF₆⁻. ...

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Figure 1: X-ray single crystal structure of ZB4 and the host–guest complexes. a) ZB4, b) 2⁺@ZB4-IV, c) 3⁺@ZB4...

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Figure 2: Parabolic free-energy relationship between log(K_R/K_H) and Hammett parameter σ_p. K_R: guests 11⁺–21⁺; ...

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Figure 3: X-ray single crystal structures of 14⁺@ZB4-III, 16⁺@ZB4-III, 18⁺@ZB4-III and 21⁺@ZB4-III. Butyl gro...

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Figure 4: X-ray single crystal structures of 18⁺@ZB4-III and 18⁺ in 18⁺@ZB4-III.

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Figure 5: Linear relationships of ΔH with temperature (left, slope = −0.13, R² = 0.9956) and TΔS (right, slop...

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Published 27 Jun 2018

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